Usage: srvctl add service -db <db_unique_name> -service "<service_name_list>" -update {-preferred "<new_pref_inst>" | -available "<new_avail_inst>"} [-force] [-verbose]
    -db <db_unique_name>           Unique name for the database
    -service "<serv,...>"          Comma separated service names
    -update                        Add a new instance to service configuration
    -preferred <new_pref_inst>     Name of new preferred instance
    -available <new_avail_inst>    Name of new available instance
    -force                         Force the add operation even though a listener is not configured for a network
    -verbose                       Verbose output
    -help                          Print usage
--集群添加service
[oracle@p19c01 ~]$ srvctl add service -d orcl -s spdb01 -pdb pdb01 -preferred orcl1 -available orcl2
[oracle@p19c01 ~]$ srvctl config service -d orcl -s spdb01
Service name: spdb01
Server pool: 
Cardinality: 1
Service role: PRIMARY
Management policy: AUTOMATIC
DTP transaction: false
AQ HA notifications: false
Global: false
Commit Outcome: false
Failover type: 
Failover method: 
Failover retries: 
Failover delay: 
Failover restore: NONE
Connection Load Balancing Goal: LONG
Runtime Load Balancing Goal: NONE
TAF policy specification: NONE
Edition: 
Pluggable database name: pdb01
Hub service: 
Maximum lag time: ANY
SQL Translation Profile: 
Retention: 86400 seconds
Replay Initiation Time: 300 seconds
Drain timeout: 
Stop option: 
Session State Consistency: DYNAMIC
GSM Flags: 0
Service is enabled
Preferred instances: orcl1
Available instances: orcl2
CSS critical: no

--TNS添加SPDB01
[oracle@p19c01 ~]$ cd $ORACLE_HOME/network/admin
[oracle@p19c01 admin]$ cat tnsnames.ora 
SPDB01 =
  (DESCRIPTION =
    (ADDRESS = (PROTOCOL = TCP)(HOST = p19c-scan)(PORT = 1521))
    (CONNECT_DATA =
      (SERVER = DEDICATED)
      (SERVICE_NAME = spdb01)
    )
  )
--启动service
[oracle@p19c01 admin]$ srvctl start service -d orcl -s spdb01
[oracle@p19c01 admin]$ lsnrctl stat
Service "spdb01" has 1 instance(s).
  Instance "orcl1", status READY, has 1 handler(s) for this service...
The command completed successfully
--连接pdb01
[oracle@p19c01 admin]$ tnsping spdb01

TNS Ping Utility for Linux: Version 19.0.0.0.0 - Production on 20-MAR-2021 06:41:43

Copyright (c) 1997, 2019, Oracle.  All rights reserved.

Used parameter files:


Used TNSNAMES adapter to resolve the alias
Attempting to contact (DESCRIPTION = (ADDRESS = (PROTOCOL = TCP)(HOST = p19c-scan)(PORT = 1521)) (CONNECT_DATA = (SERVER = DEDICATED) (SERVICE_NAME = spdb01)))
OK (0 msec)
[oracle@p19c01 admin]$ sqlplus admin/oracle@spdb01

SQL*Plus: Release 19.0.0.0.0 - Production on Sat Mar 20 06:41:53 2021
Version 19.3.0.0.0

Copyright (c) 1982, 2019, Oracle.  All rights reserved.

Last Successful login time: Sat Mar 20 2021 06:06:05 +08:00

Connected to:
Oracle Database 19c Enterprise Edition Release 19.0.0.0.0 - Production
Version 19.3.0.0.0

ADMIN@spdb01> show user
USER is "ADMIN"
ADMIN@spdb01> show con_name

CON_NAME
------------------------------
PDB01

?